free-radical initiator

  • 1Free radical addition — is an addition reaction in organic chemistry involving free radicals [L.G. Wade s Organic Chemistry 5th Ed. (p 319) Mechanism supplements original.] . The addition may occur between a radical and a non radical, or between two radicals.The basic… …

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  • 2Free radical reaction — A free radical reaction is any chemical reaction involving free radicals. This reaction type is abundant in organic reactions. Two pioneering studies into free radical reactions have been the discovery of the triphenylmethyl radical by Moses… …

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  • 3Radical initiator — In chemistry, radical initiators are substances that can produce radical species under mild conditions and promote radical polymerization reactions. These substances generally possess weak bonds mdash;bonds that have small bond dissociation… …

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  • 4Living free radical polymerization — is a type of living polymerization where the active polymer chain end is a free radical. Several methods exist. IUPAC recommends[1] to use the term reversible deactivation radical polymerization instead of living free radical polymerization .… …

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  • 5Controlled Free Radical Polymerization — Die Controlled Free Radical Polymerization (CFRP) oder Living Free Radical Polymerization (LFRP) (kontrollierte freie radikalische Polymerisation bzw. lebende freie radikalische Polymerisation) ist ein Polymerisations Verfahren, bei dem durch… …

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  • 6Radical polymerization — is a type of polymerization in which the reactive center of a polymer chain consists of a radical.The polymerization reaction is initiated by three classes of free radical initiators: * certain compounds that can be broken down in two radicals at …

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  • 7Radical-nucleophilic aromatic substitution — or SRN1 in organic chemistry is a type of substitution reaction in which a certain substituent on an aromatic compound is replaced by a nucleophile through an intermediary free radical species:The substituent X is a halide and nucleophiles can be …

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  • 8Radical substitution — In organic chemistry, a radical substitution reaction is a substitution reaction involving free radicals as a reactive intermediate. The reaction always involves at least two steps, and possibly a third. In the first step called initiation a free …

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  • 9Cobalt mediated radical polymerization — Cobalt based catalysts, when used in radical polymerization, have several main advantages especially in slowing down the reaction rate, allowing for the synthesis of polymers with peculiar properties. As starting the reaction does need a real… …

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  • 10Oxygen radical absorbance capacity — (ORAC) is a method of measuring antioxidant capacities in biological samples in vitro.[1][2] A wide variety of foods has been tested using this method, with certain spices, berries and legumes rated highly.[3] There exists no physiological proof… …

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