metalation
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Metalation — (metallation) is a chemical reaction which results in a metal atom being attached to a (usually organic) molecule. Lithium metal in contact with an organohalide lithiates the organic molecule and gives the organolithium reagent and lithium halide … Wikipedia
metalation — ▪ chemical process any chemical process by which a metal atom is introduced into an organic molecule to form an organometallic compound, but more commonly the process involving a hydrogen–metal exchange. An example is the metalation of… … Universalium
metalation — noun Any chemical reaction in which a hydrogen atom is replaced by one of a metal … Wiktionary
metalation — met·al·a·tion … English syllables
metalation — ˌ ̷ ̷ ̷ ̷ˈāshən noun ( s) Etymology: metal (I) + ation : the process of attaching a metal atom to a carbon atom of an organic molecule … Useful english dictionary
Directed ortho metalation — (DoM) is an adaptation of electrophilic aromatic substitution in which electrophiles attach themselves exclusively to the ortho position of a direct metalation group or DMG through the intermediary of an aryllithium compound [1]. The DMG… … Wikipedia
Organolithium reagent — An organolithium reagent is an organometallic compound with a direct bond between a carbon and a lithium atom. As the electropositive nature of lithium puts most of the charge density of the bond on the carbon atom, effectively creating a… … Wikipedia
N-Butyllithium — Chembox new Name = n Butyllithium ImageFile = N butyllithium tetramer 3D balls.png ImageName = 3D ball and stick model of n butyllithium IUPACName = butyllithium, tetra μ3 butyl tetralithium OtherNames = NBL, BuLi, 1 lithiobutane Section1 =… … Wikipedia
Ortho-Metallierung — Unter einer Ortho Metallierung (oder auch englisch directed ortho metallation und abgekürzt DoM) versteht man die Metallierung von entsprechend substituierten Aromaten mit Alkyllithiumverbindungen. Die Substituenten werden als direct metalation… … Deutsch Wikipedia
n-Butyllithium — hexamer IUPAC name … Wikipedia
Smiles rearrangement — The Smiles rearrangement is an organic reaction and a rearrangement reaction. [A. A. Levy, H. C. Rains and S. Smiles, J. Chem. Soc. 1931, 3264.] It is an intramolecular nucleophilic aromatic substitution of the type:where X in the arene compound… … Wikipedia
