- cyclic rearrangement
- циклическая перестановка
Большой англо-русский и русско-английский словарь. 2001.
Большой англо-русский и русско-английский словарь. 2001.
Cyclic order — In mathematics, a cyclic order is a way to arrange a set of objects in a circle.[nb] Unlike most structures in order theory, a cyclic order cannot be modeled as a binary relation a < b . One does not say that east is more clockwise than west.… … Wikipedia
Rearrangement reaction — A rearrangement reaction is a broad class of organic reactions where the carbon skeleton of a molecule is rearranged to give a structural isomer of the original molecule.[1] Often a substituent moves from one atom to another atom in the same… … Wikipedia
Réarrangement de Wolff — Le réarrangement de Wolff est une réaction de réarrangement d une α diazo cétone en cétène[1],[2],[3]. Cette réaction a été décrite la première fois par Ludwig Wolff en 1912 … Wikipédia en Français
Beckmann rearrangement — The Beckmann rearrangement, named after the German chemist Ernst Otto Beckmann (1853–1923), is an acid catalyzed rearrangement of an oxime to an amide. [cite journal author= E. Beckmann title = Zur Kenntniss der Isonitrosoverbindungen journal =… … Wikipedia
1,2-rearrangement — A 1,2 rearrangement or 1,2 migration or 1,2 shift or Whitmore 1,2 shift cite journal | title = The common basis of molecular rearrangements | first = Frank C. | last = Whitmore | journal = J. Am. Chem. Soc. | date = 1932 | volume = 54 | issue = 8 … Wikipedia
Divinylcyclopropane-cycloheptadiene rearrangement — The divinylcyclopropane cycloheptadiene rearrangement is an organic chemical transformation that involves the isomerization of a 1,2 divinylcyclopropane into a cycloheptadiene or triene. It is conceptually related to the Cope rearrangement, but… … Wikipedia
Tiffeneau–Demjanov rearrangement — The Tiffeneau Demjanov rearrangement (TDR) is the chemical reaction of a 1 aminomethyl cycloalkanol with nitrous acid to form an enlarged cycloketone. The Tiffeneau–Demjanov ring expansion, Tiffeneau–Demjanov rearrangement, or TDR, provides an… … Wikipedia
Di-pi-methane rearrangement — The di pi methane rearrangement is a photochemical reaction of a molecular entity comprising two π systems, separated by a saturated carbon atom (a 1,4 diene or an allyl substituted aromatic analog), to form an ene (or aryl ) substituted… … Wikipedia
Newman–Kwart rearrangement — The Newman–Kwart rearrangement is a type of rearrangement reaction in which the aryl group of an O aryl thiocarbamate, ArOC(=S)NMe2, migrates from the oxygen atom to the sulfur atom, forming an S aryl thiocarbamate, ArSC(=O)NMe2.[1][2][3] The… … Wikipedia
Pinacol rearrangement — The pinacol rearrangement or pinacol pinacolone rearrangement is a method for converting a 1,2 diol to a carbonyl compound in organic chemistry. This rearrangement takes place under acidic conditions. The name of the reaction comes from the… … Wikipedia
Brook rearrangement — The Brook rearrangement in organic chemistry is a rearrangement reaction in which a organosilyl group switches position with a hydroxyl proton over a carbon to oxygen covalent bond under the influence of a base [cite journal | author = A. G.… … Wikipedia