gauche conformation
1gauche conformation — sinklininė konformacija statusas T sritis chemija apibrėžtis Konformacija, kurios gretimų C atomų du pakaitai yra (+60 ± 30)° arba (−60 ± 30)° Niumeno projekcijos sektoriuje. atitikmenys: angl. gauche conformation; partially staggered… …
2Gauche effect — Main article: alkane stereochemistry The term gauche refers to conformational isomers (conformers) where two vicinal groups are separated by a 60° torsion angle. IUPAC defines groups as gauche if they have a synclinal alignment of groups attached …
3gauche — adjective (sometimes gaucher; sometimes gauchest) Etymology: French, literally, left Date: 1751 1. a. lacking social experience or grace; also not tactful ; crude < it would be gauche to mention the subject > b. crudely made or …
4partially-staggered conformation — sinklininė konformacija statusas T sritis chemija apibrėžtis Konformacija, kurios gretimų C atomų du pakaitai yra (+60 ± 30)° arba (−60 ± 30)° Niumeno projekcijos sektoriuje. atitikmenys: angl. gauche conformation; partially staggered… …
5skew conformation — sinklininė konformacija statusas T sritis chemija apibrėžtis Konformacija, kurios gretimų C atomų du pakaitai yra (+60 ± 30)° arba (−60 ± 30)° Niumeno projekcijos sektoriuje. atitikmenys: angl. gauche conformation; partially staggered… …
6synclinal conformation — sinklininė konformacija statusas T sritis chemija apibrėžtis Konformacija, kurios gretimų C atomų du pakaitai yra (+60 ± 30)° arba (−60 ± 30)° Niumeno projekcijos sektoriuje. atitikmenys: angl. gauche conformation; partially staggered… …
7Cyclohexane conformation — A cyclohexane molecule in chair conformation. Hydrogen atoms in axial positions are shown in red, while those in equatorial positions are in blue. A cyclohexane conformation is any of several three dimensional shapes that a cyclohexane molecule… …
8Alkane stereochemistry — concerns the stereochemistry of linear alkanes and the linear alkane conformers. The existence of more than one conformation is due to hindered rotation around sp3 hybridised carbon carbon bonds. The smallest molecule with such a chemical bond,… …
9Pentane interference — or syn pentane interaction is the steric hindrance that the two terminal methyl groups experience in one of the chemical conformations of n pentane. The possible conformations are combinations of anti conformations and gauche conformations and… …
10Glucose — This article is about the naturally occurring D form of glucose. For the L form, see L Glucose. D glucose …
